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Q.

The molar conductivities of KC!, KNO3 , HCl, NaOAc and NaCl are 149.9, 145.0, 426.2, 91.0 and 126.5 S cm2 mol-1, respectively. The molar conductivity at infinite dilution of acetic acid will be

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a

390.7 S cm2 mol-1

b

217.5 S cm2 mol-1

c

 552.7 S cm2  mol-1 

d

517.2 S cm2 mol-1

answer is A.

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Detailed Solution

We have

 Λm(HOAc)=Λm(NaOAc)+Λm(HCl)Λm(NaCl) =(91.0+426.2126.5) S cm2mol1 =390.7 S cm2mol1

The molar conductivity at infinite dilution of acetic acid will be 390.7 S cm2 mol-1

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