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Q.

The molar conductivity of acetic acid at infinite dilution is 390.7 Scm2 mol-1 and for 0.01 M acetic acid is
3.907 Scm2 mol-1. The degree of dissociation and pH of the solution is ?

 (α)pH
10.13
20.024
30.0015
40.014

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a

2

b

1

c

3

d

4

answer is D.

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Detailed Solution

Degree of dissociation

(α)=mm0=3.907390.7=0.01

CH3COOH     CH3COO+H+

Initial conc.   C              0                  0

Final conc.  C(1α)   Cα              Cα

So,  [H+]=Cα=0.01×0.01=104M

pH=log[H+]=log104

pH=4

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The molar conductivity of acetic acid at infinite dilution is 390.7 Scm2 mol-1 and for 0.01 M acetic acid is3.907 Scm2 mol-1. The degree of dissociation and pH of the solution is ? (α)pH10.1320.02430.001540.014