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Q.

The molar heat capacity, Cv of helium gas is 3/2 R and is independent of temperature. For hydrogen gas, Cv  approaches 3/2 Rat very low temperature, equals 5 / 2 R at moderate temperatures and is higher than 5 / 2 R at high temperature. Choose the correct reason for the temperature dependence of Cv in case of hydrogen:

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a

Hydrogen is diatomic so at high temperature rotational and vibrational motion are not counted.

b

Can't be defined.

c

Hydrogen is diatomic so at high temperature rotational and vibrational motion also counts.

d

Hydrogen is monoatomic so at high temperature rotational and vibrational motion also counts.

answer is A.

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Detailed Solution

Molar heat capacity does not depends on the temperature.

Hydrogen is diatomic so at high temperature rotational and vibrational motion are counts.

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