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Q.

The molar solubility of CaF2 Ksp=5.3×1011in 0.1 M solution of NaF will be

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a

5.3x10-10mole lit-1

b

5.3x10-11mole lit-1

c

5.3x10-8mole lit-1

d

5.3x10-9mole lit-1

answer is D.

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Detailed Solution

            CaF2Ca+2+2F
At equili.              S        2S
NaFNa++F
0.1       0.1      0.1
Due to common ion effect of NaF, solubility of CaF2 is further suppressed. Therefore the concentration of F- will be mainly due to NaF
Ksp=Ca+2F2Ksp=(S)(0.1+2S)2 ( or ) (0.1+2S0.1)Ksp=(S)(0.1)2
S=5.3×1011(0.1)2=5.3×109 molelit 1

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