Q.

The molar solubility of CdOH2 is 1.84×105 M in water.  The expected solubility of CdOH2  in a buffer solution of pH = 12 is 

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a

1.84×109M

b

2.49×1010M

c

2.49/1.84×109M

d

6.23×1011M

answer is B.

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Detailed Solution

Given molar solubility,  s=1.84×105
Ksp=4s3=41.84×1053
 CdOH2Cd2++2OH
  s' represent the solubility in buffer solution 
pH = 12,  pOH = 2
 OH=102
So,  s'=2.492×1010moles  L1

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The molar solubility of CdOH2 is 1.84×10−5 M in water.  The expected solubility of CdOH2  in a buffer solution of pH = 12 is