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Q.

The molar solubility of  Ni(OH)2 in 0.10M  NaOH solutions is x× 10-13 . The ionic product of NiOH 2 is 2.0×10-15 . Value of x is (pkw=14)

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answer is 2.

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Detailed Solution

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First Method
For bi-univalent type  Ni(OH)2
 ksp=4s3SH2O=(ksp4)1/3Snew=ksp[OH]2=2.0×1015(0.10)2=2.0×1013M[Ni2+]=2.0×1013M
Second method
Let the solubility of Ni(OH)2  is S. Dissolution of S mol. L1  of Ni(OH)2 provides S mol L1 and 2Smol1  of[OH]   ions but the total concertation of [OH]=(0.10+2S)mol.L1  because the solution already contains 0.1mol.L1  from  NaOH
 ksp=2.0×1015=[Ni2+][OH]2=(S)(0.10+2S)2As  ksp  is  small2S<<0.10Thus(0.10+2S)=0.10Hence2.0×1015=S(0.10)h2S=2.0×1013M=[Ni2+]

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