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Q.

The molar solubility of CdOH2 is 1.84×10-5 M in water. The expected solubility of CdOH2 in a buffer solution of pH=12 is:

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a

2.49×10-10M

b

6.23×10-11M

c

1.84×10-9M

d

2.491.84×10-9M

answer is D.

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Detailed Solution

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CdOH2Cd2+s+2OH-2S At equilibrium,

Ksp=s2s2=4s3

Solubility in buffer solution having pH=12OH-=10-2 CdOH2Cd2+s'+2OH-2S+10-210-2 Ksp=4×1.84×10-53=s'10-22 s'=24.9×10-1510-4=2.49×10-10M

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