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Q.

The molar specific heat of a gas as given from the kinetic theory is  52R.  If it is not specified whether it is Cp or Cv, one could conclude that the molecules of the gas.

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a

are definitely monoatomic

b

are definitely rigid diatomic

c

are definitely non-rigid diatomic

d

can be monoatomic or rigid diatomic

answer is D.

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Detailed Solution

A monoatomic gas has 3 degrees of freedom and diatomic gas has 5 degrees of freedom.
For monoatomic gas,

CV=32R and Cp=CV+R=32R+R=52R

For a diatomic gas,

CV=52R and Cp=CV+R=52R+R=7R2

Hence, we can conclude that the molecules of the gas can be monoatomic or rigid diatomic.

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