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Q.

The molarity of H3PO4(d=1.8g/mL) is 18 M. Hence, mass percentage and molality are: 

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a

98, 500

b

98, 18

c

18, 32.4

d

98, 32.4

answer is C.

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Detailed Solution

Density = 1.8 g/mL
Molarity = 18 M = 18 mol H3PO4 in 1 L solution
1000 mL solution has H3PO4= 18 mol = 18 × 98 g
100 mL = (1800 g) solution has H3PO4 = 18 × 98 g
H3PO4 by mass o/o (by weight of solution) 

=18×981800×100=98%

or (180018×98)gH2O (solvent) H3PO4=18×98g

2g solvent has H3PO4=98g=1molH3PO4

1g=1000g solvent has H3PO4=500 molal 

Thus, 98%, 500 molal.

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