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Q.

The molecular formulas of various hexacordinates are given as below.
(a) CrCl3.6NH3  (b) CrCl3.5NH3 
(c) CrCl3.4NH 
If the number of NH3 ligands attached to the central metal ion respectively are 6, 5 and 4, then the number of Cl- ions showing dual character in (a), (b) and (c) respectively are:

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a

3, 3, 3

b

0, 1, 2

c

3, 2, 1

d

6, 5, 4

answer is B.

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Detailed Solution

Dual character  of the above complexes are 0, 1, 2 respectively.
[Cr(NH3)6]Cl3,[Cr(NH3)5Cl]Cl2,[Cr(NH3)4Cl2]Cl

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