Q.

The molecular weight of a gas which diffuses through a porous plug at 16th of the speed of hydrogen under identical conditions is

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a

12

b

72

c

64

d

36

answer is B.

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Detailed Solution

Let us assume the rate of diffusion of hydrogen gas isr1

The rate of diffusion of other gas with molecular mass M2 to be r2

Then r2=16r1

According to Graham’s law of diffusion

r α1M

According to Graham’s law of diffusion

r1r2=MMH2

r16r=M2

6=M2

Take square on both sides of the above equation

M2=36

M = 72

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