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Q.

The molecule (SiH3)3N is

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a

Planar and more basic than (CH3)3N

b

Pyramidal and more basic than (CH3)3N

c

Planar and less basic than (CH3)3N

d

Pyramidal and less basic than (CH3)3N

answer is B.

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Detailed Solution

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(SiH3​)3​N is planar and less basic than (CH3​)3​N because lone pair of N atom is used to form pπ−dπ back bonding with Si-atom which is not possible by carbon atom due to absence of d-orbital.

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The molecule (SiH3)3N is