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The molecule with sixteen lone pairs is

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SF₆

BrF₅

XeF₄

XeF₂

answer is C.

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Detailed Solution

bold Number bold space bold of bold space bold electron bold space bold pairs bold left parenthesis bold EP bold right parenthesis bold equals fraction numerator V bold and italic M bold minus sign C bold and italic A over denominator bold 2 end fraction bold semicolon
V bold equals bold Group bold space bold number bold space bold of bold space bold central bold space bold atom bold semicolon
italic M bold equals bold minus sign H bold comma bold space bold minus sign italic X bold comma bold space bold minus sign O H bold point bold point bold point bold point bold monovalent bold space bold groups bold space bold attached bold space bold to bold space bold central bold space bold atom bold space bold semicolon
C bold equals bold Charge bold space bold of bold space bold cation bold space bold semicolon
italic A bold equals bold Charge bold space bold of bold space bold anion bold space bold semicolon
V bold equals bold 6 bold comma bold 7 bold comma bold 8 bold space bold respectively bold space bold for bold space bold 16 to the power of bold th bold comma bold space bold space bold 17 to the power of bold th bold comma bold space bold 18 to the power of bold th bold space bold group bold space bold elements bold space bold semicolon
bold Number bold space bold bond bold space bold pairs bold comma bold space B P bold left parenthesis bold according bold space bold to bold space bold VSEPR bold space bold theory bold right parenthesis bold equals bold Number bold space bold of bold space bold atoms bold space bold directly bold space bold attached bold space bold to bold space bold central bold space bold atom bold semicolon
bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold equals bold 6 bold comma bold 5 bold comma bold 4 bold comma bold space bold respectively bold space bold in bold space S F subscript bold 6 bold comma bold space Br F subscript bold 5 bold comma bold space Xe F subscript bold 4 bold space bold semicolon
Number space lone space pairs space on space central space atom bold left parenthesis bold LP bold right parenthesis equals bold EP bold minus sign B P bold space bold semicolon bold space
space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space equals bold 0 bold comma bold 1 bold comma bold 2 bold space bold respectively bold space bold in space S F subscript bold 6 bold comma bold space Br F subscript bold 5 bold comma bold space Xe F subscript bold 4 bold space bold semicolon
S F subscript bold 6 bold minus sign bold apostrophe bold 6 bold apostrophe bold space bold bp bold space bold plus bold apostrophe bold 0 bold apostrophe bold space bold lp bold space bold on bold space bold central bold space bold atom bold semicolon bold space bold sp to the power of bold 3 italic d to the power of bold 2 bold minus sign bold Squre bold space bold bipyramidal bold space begin bold style open parentheses or close parentheses end style bold space bold Octahedral bold space bold semicolon bold space bold 18 bold space bold lone bold space bold pairs bold forward slash bold molecule
Br F subscript bold 5 bold minus sign bold apostrophe bold 5 bold apostrophe bold space bold bp bold space bold plus bold apostrophe bold 1 bold apostrophe bold space bold lp bold space bold on bold space bold central bold space bold atom bold space bold semicolon bold space bold sp to the power of bold 3 italic d to the power of bold 2 bold minus sign bold Squre bold space bold pyramidal bold space bold semicolon bold space bold 16 bold space bold lone bold space bold pairs bold forward slash bold molecule
Xe F subscript bold 4 bold minus sign bold apostrophe bold 4 bold apostrophe bold space bold bp bold space bold plus bold apostrophe bold 2 bold apostrophe bold space bold lp bold space bold on bold space bold central bold space bold atom bold space bold semicolon bold space bold sp to the power of bold 3 italic d to the power of bold 2 bold minus sign bold Square bold space bold planar bold space bold semicolon bold space bold 14 bold space bold lone bold space bold pairs bold forward slash bold molecule
bold Note bold semicolon bold space bold Each bold space bold bonded bold space bold halogen bold space bold atom bold space bold has bold space bold apostrophe bold 3 bold apostrophe bold space bold lone bold space bold pairs bold space bold on bold space bold it bold space bold semicolon
bold Orientation bold space bold of bold space bold electron bold space bold pairs bold space bold is bold space bold octahedral bold space begin bold style open parentheses or close parentheses end style bold space bold Square bold space bold bipyramidal bold space bold in bold space bold all bold space bold the bold space bold three bold space bold molecules bold space bold semicolon

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