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Q.

The mononuclear complex salt having the molecular composition [Co(en)2 (SCN) (NO2)] Br can exist in a number of isomeric forms. The total number of possible isomers of all types is

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a

six

b

nine

c

twelve

d

twenty-four

answer is D.

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Detailed Solution

  • [Co(NO2)(SCN)(en)2]Br is an octahedral complex of the type of octahedral complex show geometrical isomerism.
  • Since the group Br outside the coordination can be interchanged with the ligands, so it gives different ions in the solution and hence, this compound will also show ionization isomerism.
  • Since the coordination sphare of the complex ion has ambident ligands such as SCN and NO2, therefore, the compound would also show linkage isomerism
  • .total  24 isomers 
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