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Q.

The most basic one is :

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a

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b

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c

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d

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answer is D.

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Detailed Solution

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Due to hyperconjugation and +I effect.

Basicity depends on the negative charge on the nitrogen atom or electron density. With an increase in the -ve charge on the nitrogen atom, the basicity of the amines increases. Basicity depends on charge density. Basicity decreases with a decrease in charge density.Resonance and inductive effects decrease the basicity of an amine.  Plus I effect will increase the basicity.
 

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The most basic one is :