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Q.

The most stable carbocation amongst the following is:

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a

CH3C=NH

b

CH3CH2

c

(CH3)2CH

d

CH3C=O

answer is C.

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Detailed Solution

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The positively charged carbon atom in the carbocation is sp2 hybridised. This part of the carbocation is planar and the vacant p- orbital is perpendicular to this plane. The shape of methyl carbocation is trigonal planar.

A carbocation having plus I groups or electron donating groups will be more stable. Less electro negative elements will have more donating ability.

 

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