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Q.

The most stable complex entity is :

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a

CoF63-

b

[Co(H2O)6 ]3+

c

[Co(NH3 )6 ]3+

d

[Co(CN )6 ]3-

answer is D.

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Detailed Solution

  • In all compounds, central metal is same but ligands are different.
  • From ligand strength, we can see that CN− is strongest ligand among all. 
  • So, [Co(CN)6​]3− is most stable complex ion.
  • Ligand field strength :  F-< H2O < NH3 < CN- 
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The most stable complex entity is :