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Q.

The n – factor of MnO4 in the following change   3MnO42Mn2++Mn+6

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a

23

b

34

c

113

d

45

answer is C.

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Detailed Solution

n-Factor Calculation for MnO4-

In the reaction:
3 MnO4- → 2 Mn2+ + Mn6+

Oxidation State Changes:

  • Mn in MnO4-: +7
  • For 2 Mn converted to Mn2+: 2 × (7 – 2) = 10 electrons gained
  • For 1 Mn converted to Mn6+: 1 × (7 – 6) = 1 electron gained
  • Total electrons transferred for 3 Mn: 10 + 1 = 11
  • n-Factor per MnO4- ion: 11 / 3

Final answer: n-factor = 11/3

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