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Q.

The n-factor for Ferrocyanide in the reaction given below: Fe(CN)64-Fe3++CO2+NO3-1 is

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a

61

 

b

2

c

32

d

56

answer is D.

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Detailed Solution

The oxidation state of iron in reactant is +2 and in product is +3, net loss of electrons is 1.

The oxidation state of carbon in reactant is +2 and in product is +4, net loss of electrons is 2.

The oxidation state of nitrogen in reactant is -3 and in product is +5, net loss of electrons is 8.

Overall reaction is oxidation.

There are 6 carbons and nitrogen in the reactant, therefore the n-factor is

Fe(CN)64-=[(1×1)+(6×2)+(6×8)=61

Hence, the correct option is D.

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