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Q.

The normal boiling point of a liquid X is 400 K. Which of the following statement is true about the process, X(l) X(g)?

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a

At 400 K and 1 atm pressure, ΔG=0

b

At 400 K and 2 atm pressure, ΔG=+ve

c

At 400 K and 0.1 atm pressure, ΔG=ve

d

At 410 K and 1 atm pressure, ΔG=+ve

answer is A.

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Detailed Solution

At 400 K, system is in equilibrium and at equilibrium point, ΔG=0. Therefore, at 400 ΔG=0 
At 400 K and 2 atm pressure, the system has boiling point more than 400 K, so at this point the system will be non- spontaneous, ΔG=+ve.
At 400 K and 0.1 atm pressure, the system has boiling point less than 400 K, so at this point the system will be spontaneous, ΔG=ve.

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