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Q.

The normal boiling point of a liquid ‘X’ is 400K. Which of the following statement is true about the process X(l) X(g)

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a

at 400K and 1 atm pressure ΔG=0

b

at 400K and 2 atm pressure ΔG=+ve

c

at 400K and 0.1 atm pressure  ΔG=ve

d

at 410K and 1 atm pressure ΔG=+ve

answer is A, B, C.

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Detailed Solution

at 400°K (1 atm) system is at equilibrium, hence ΔG=0

At 400K 2 atm pressure liquid does not boil and it is non spontaneous process (ΔG = + ve)

At 400K and 0.1 atm pressure, liquid boil and it is spontaneous hence (ΔG=ve)

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The normal boiling point of a liquid ‘X’ is 400K. Which of the following statement is true about the process X(l) → X(g)