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Q.

The number of correct statements among the following is

1) Both  MnO4  and  MnO42  are having tetrahedral structure
2) Purple MnO42   is paramagnetic and green MnO4  is diamagnetic 
3)  MnO42 Exhibit color due to d-d transitions  
4) MnO4  Oxidizes I   to  IO3  in alkaline medium  
5) Number of moles of  K2Cr2O7  reduced by 1 mole of  Sn2+  is 1/3
 

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answer is 4.

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Detailed Solution

MnO4 is purple in colour, tetrahedral shaped and diamagnetic whereas MnO42  is green in colour, tetrahedral shaped and paramagnetic.

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