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Q.

The number of incorrect statement from the following is ……….
A. The electrical work that a reaction can perform at constant pressure and temperature is equal to the reaction Gibbs energy 

B. Ecello is dependent on the pressure
C. dEcell dT=ΔrSnF
D. A cell is operating reversibly if the cell potential is exactly balanced by an opposing source of potential difference

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answer is 2.

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Detailed Solution

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A,D are incorrect

When the external voltage is equal to the electrical potential of the cell, there will be no flow of electrons or current. Also, no chemical reaction.

Relation between Electrochemical Cell Potential and Gibbs free Energy change is given by; Δ G = -nFEo 

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