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Q.

The number of molecules with energy greater than the threshold energy for a reaction increases five fold by a rise of temperature from  27°C to 42°C. Its energy of activation in KJ/mol is _____. (Take ln 5 = 1.6094; R = 8.314 Jmol1K1)

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a

52.42

b

46.15

c

23.32

d

84.32

answer is C.

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Detailed Solution

r2r1=eE2/RT2eE2/RT1=5ln5=EaRT2T1T1T22.303×0.6990=Ea8.31415300×315Ea=84.32 KJ 

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