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Q.

The number of moles of CuO, that will be utilized in Dumas method for estimating nitrogen in a sample of 57.5 g of N,N-dimethylaminopentane is __ × 10–2. (Nearest integer)

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answer is 1125.

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Detailed Solution

Given data : It is given to find the number of moles of CuO, that will be utilized in Dumas method for estimating nitrogen in a sample of 57.5 g of N,N-dimethylaminopentane is __ × 10–2. (Nearest integer).

Explanation:

N,N-dimethylaminopentane is C7H17N, i.e. (CH3)2N-(CH2)4-CH3.
The reaction would be as follows :
C7H17N + 452CuO 7 CO2172H2O + 12N2452Cu
Moles of nitrogen in the given compound = Given MassMolecular Mass  = 57.5115 mole = 0.5 mole
From the balanced chemical equation,
1 mole of C7H17N requires  = 22.5 mole of CuO
0.5 mole of C7H17N requires  = 22.5 * 0.5 mole of CuO = 11.25 = 1125 X 10-2

Hence, the correct answer is 1125.

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