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Q.

The number of moles of KI required to prepare one mole of K2[HgI4] is

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a

2

b

1

c

3

d

4

answer is A.

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Detailed Solution

The formation of K2[HgI4] from KI is a two-step process.
Step-1: Potassium iodide reacts withHgCl2(Mercuric chloride) and forms HgI2(Mercuric Iodide).
2KI+HgCl2→HgI2+2KCl
Step-2: The formedHgI2(Mercuric Iodide) reacts with excess amount of KI and forms potassium mercuric iodide (K2[HgI4]).
HgI2+2KI→K2[HgI4] potassium mercuric iodide
-The overall reaction can be written as follows.
4KI+HgCl2→ K2[HgI4]+2KCl
From the above equation we can say that four moles of potassium iodide reacts with Mercuric iodide and forms one mole ofK2[HgI4](potassium mercuric iodide).

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