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Q.

The number of moles of MnO_4  and Cr2O72 separately required to oxidize 1 mole of FeC2O4 each in acidic medium respectively

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a

0.5, 0.5

b

0.6, 0.4

c

0.6, 0.5

d

0.5, 0.6

answer is C.

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Detailed Solution

3MnO¯4+5FeC2O4+24H+3Mn2++5Fe3++10CO2+12H2O

3 moles of MnO¯4= 5 moles of FeC2O4

                    ?          =1 moles of FeC2O4

no. of moles of MnO¯4=35

Cr2O72+2FeC2O4+14H+2Cr3++2Fe3++4CO2+7H2O

2 moles of FeC2O4 = 1 mole of Cr2O72

1 mole FeC2O4=?

no of moles of Cr2O72=12

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