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Q.

The number of moles of MnO4- and Cr2O7-2 separately required to oxidise one mole of FeC2O4 each in acidic medium respectively

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a

0.5 ; 0.6

b

0.6 ; 0.5

c

0.6 ; 0.4

d

0.4 ; 0.5

answer is D.

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Detailed Solution

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3MnO4-+5FeC2O4+24H+3Mn+2+5Fe+3+10CO2+12H2O

⟹5FeC2​O4​ reacts with 3MnO4-

⟹1 mole of FeC2​O4​=3/5​ mole of MnO4-

∴1 mole of FeC2​O4​=0.6 mole of  MnO4-

Cr2O7-2+2FeC2O4+14H+2Cr+3+2Fe+3+4CO2+7H2O

⟹2 mole of FeC2​O4​ required 1 mole of Cr2O7-2

⟹1 mole of FeC2​O4​ required 1/2​ mole of  Cr2O7-2

⟹0.5 mole of Cr2O7-2

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