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Q.

The number of moles of MnO4- and Cr2O7-2 separately required to oxidise 1 mole of FeC2O4 each in acidic medium respectively.

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a

0.4 : 0.5

b

0.5: 0.6

c

0.6 : 0.5

d

0.6 : 0.4

answer is D.

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Detailed Solution

3MnO4- + 5FeC2O4+ 24H+ 
3Mn+2 +5Fe+3+ 10CO2 + 12H2O
3moles 5moles
? (x)  1mole 
x = 35 moles  = 0.6  moles  of  MnO4-
Cr2O7-2 + 2FeC2O4 + 14H+ 
2Cr+3 + 2Fe+3 + 4CO2 + 7H2O
1 mole    2moles
? (x)    1 moles
x = 12 = 0.5 moles  of  Cr2O7-2

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