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Q.

The number of nitrogen atoms in the major organic product, Q, of the reaction given below is _____.
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answer is 3.

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Detailed Solution

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The compound shown is benzene-1,2-diamine (o-phenylenediamine) treated with sodium nitrite (NaNO₂) and concentrated HCl at 273–278 K, which is a typical setup for diazotization.

Reaction explanation:

  • Both −NH₂ groups undergo diazotization with NaNO₂/HCl to form a diazonium salt.
  • However, when phenylenediamine (with both groups ortho) is treated with nitrous acid, it forms a cyclic compound called benzotriazole as the major product.
  • Benzotriazole has a ring containing three nitrogen atoms.

Answer: The number of nitrogen atoms in the major organic product Q is 3.

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