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The number of possible mono chloro structural isomers formed on free radical mono chlorination of ${(C H_{3})}_{2} C H C H_{2} C H_{3}$ is _____________

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answer is 4.

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Detailed Solution

For 2-methylbutane

, distinct H sites:

the two equivalent methyls attached to C2 → one primary chloride,

the terminal CH $_3$ $3$ $$ at the end of the ethyl group → another primary chloride,

the CH $_2$ $2$ $$ group → a secondary chloride,

the central CH (C2) → a tertiary chloride.

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