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Q.

The number of unpaired electron in [Pt(CN)4]2– ion having square planar geometry (At.No. of Pt = 78) is

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a

2

b

1

c

0

d

3

answer is A.

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Detailed Solution

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In this complex, Pt is in the +2 state. It forms a square planar structure. This means that it undergoes dsp2 hybridization. Now, the electronic configuration of Pd(+2) is 5d8.

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CN being a strong field ligand causes the pairing of unpaired electrons. Hence, there are no unpaired electrons in

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