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Q.

The number of which are more reactive towards electrophilic substitutions than P-xylene ?
Benzene, Toulene, Mesitylene, O-xylene, m-xylene

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answer is 3.

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Detailed Solution

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Mesitylene (1,3,5-trimethyl benzene ) has three, m- xylene(1,3-dimethyl benzene) and O- xylene(1,2-dimethyl benzene) has two electron-donating CH3 groups.  

Therefore, the electron density is maximum in mesitylene, O-xylene and m-xylene. Hence, these are most reactive towards ring substitution.

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