Q.

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The observed bond angle in Ammonia is 107°48' , the expected bond angle in HPH is

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a

<107°48'

b

>107°48'

c

=107°48'

d

All

answer is B.

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Detailed Solution

Nitrogen, N and phosphorus, P belongs to VA group. In both NH3 and PH3, central atoms N and P have same hybridization sp3 with 3 B.P and 1 L.P electrons. According to VSEPR theory, we can predict the geometry and bond angle of molecules. E.N  of 'N'>E.N  of  'P' . Hence, the bond angle in HPH (<107°48°) should be less than HNH (107°48°). 

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