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Q.

The octahedral complex of a metal ion M3+ with four monodentate ligands L1,L2,L3 and L4 absorb wavelengths in the region of red, green, yellow and blue, respectively. The increasing order of ligand strength of the four ligands is

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a

L4<L3<L2<L1

b

L1<L3<L2<L4

c

L3<L2<L4<L1

d

L1<L2<L4<L3

answer is B.

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Detailed Solution

LigandL1L2L3L4

Coloured region of 

absorbed wavelength

RedGreenYellowBlue

Coloured regions of visible light (VIBGYOR) are arranged in the increasing order of wavelength or decreasing order of energy E1/λ. Therefore,

ERedL1<EYellowL2<EGreenL3<EBlueL4

This suggests that L4 will absorb higher energy wavelength followed by L2,L3 and L1. Since, higher absorbed energy corresponds to greater extent of crystal field splitting and thus, higher field strength of the ligand.
Hence, the increasing order of ligand strength of the four ligands is

L1<L3<L2<L4

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