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Q.

The octahedral complex of a metal ion  M3+with four monodentateligans L1,L2,L3 and L4absorb wavelengths  
in the region of red, green, yellow and blue, respectively.  The increasing order of ligand strength of the four ligands is 

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a

L4<L3<L2<L1

b

L1<L3<L2<L4

c

L3<L2<L4<L1

d

L1<L2<L4<L3

answer is B.

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Detailed Solution

For a given metal ion, weak field ligands create a complex with smaller Δ which will absorbs light of longer λ and thus lower frequency. Conversely, stronger field ligands create a larger absorb light of shorter  λand thus higher frequency i.e. higher energy. 

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The octahedral complex of a metal ion  M3+with four monodentateligans L1,L2,L3 and L4absorb wavelengths  in the region of red, green, yellow and blue, respectively.  The increasing order of ligand strength of the four ligands is