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The octahedral, paramagnetic and inner orbital complex among the following is

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${[N i C l_{4}]}^{2 -}$

${[C o C l_{6}]}^{3 -}$

${[C o F_{6}]}^{3 -}$

${[C r {(N H_{3})}_{6}]}^{3 +}$

answer is D.

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Detailed Solution

${[C o {(N H_{3})}_{6}]}^{3 +}$
$N H_{3} \Rightarrow S F L, C o^{+ 3} = [A r] 3 d^{6}, t_{2 g}^{6} e_{g}^{0}$
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$∴$ Diamagnetic & Low spin complex.

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