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Q.

The one that is not expected to show isomerism is

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a

${[Ni (en)_{3}]}^{+ 2}$

b

${[{NiCl}_{4}]}^{- 2}$

c

$[Pt {({NH}_{3})}_{2} {Cl}_{2}]$

d

${[Ni {({NH}_{3})}_{4} {(H_{2} O)}_{2}]}^{+ 2}$

answer is C.

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Detailed Solution

${[{NiCl}_{4}]}^{- 2}$ has tetrahedral geometry. Hence, it does not exhibit isomerism due to the presence of symmetry elements.

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