Q.

The optical rotation of  αD fructose is  210  and that of its β-form is 1330. The equilibrium mixture of these anomers has an optical rotation of  920.  What is the % of  α-form (upto one decimal place) in its equilibrium mixture?

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answer is 36.6.

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Detailed Solution

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Let x be the % of  α-form in the equilibrium  21x133100x=92×100 x=36.6%

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