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Q.

The order of basic strength of the following in aqueous solution is

NH3,C2H5NH2,C2H52NH,C2H53 N

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a

C2H53 N>C2H52NH>C2H5NH2>NH3

b

C2H52NH>C2H53 N>C2H5NH2>NH3

c

C2H53 N>C2H5NH2>C2H52NH>NH3

d

NH3>H2NC2H5>NC2H53>HNC2H52

answer is B.

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Detailed Solution

  • Aliphatic amines are stronger bases than ammonia because of inductive effect. Due to steric factors tertiary amines are less basic than primary amines. So, the order of basic strength 

C2H52NH>C2H53 N>C2H5NH2>NH3 

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