Q.

The order of basic strength of C6H5NH2(1),C2H5NH2(2),C2H52NH (3), and NH4 (4) is;

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a

 1<3<2<4

b

 1<4<2<3

c

 3<2<4<1

d

 4<2<3<1

answer is A.

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Detailed Solution

 The basicity of aniline is lower than that of ammonia because the lone pair of electrons on N in aniline is involved in resonance with the benzene ring. Because of the presence of electron-releasing ethyl groups ( + l effect), ethyl amine and diethyl amine are more basic than ammonia, and the lone pair of electrons on nitrogen can be easily transferred.

Thus, the correct order of basic strength is -C6H5NH2<NH4<C2H5NH2<C2H52NH.

Hence, the correct answer is option A) 1<4<2<3.

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