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Q.

The order of Cl-O bond energy in ClO,
ClO2, ClO3, ClO4 is

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a

ClO3 > ClO– > ClO2 > ClO4

b

ClO4 > ClO3 > ClO2 > ClO

c

ClO4 > ClO2 > ClO3 > ClO

d

ClO > ClO2> ClO3- > ClO4

answer is B.

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Detailed Solution

Question ImageExcept in hypochlorite, all these anions are stabilised by resonance structures. Perchlorate ion has four canonical structures and is most stable.so bond order increases, then bond energy increases

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The order of Cl-O bond energy in ClO–, ClO2–, ClO3–, ClO4– is