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Q.

The order of energy absorbed which is responsible for the color of complexes.
(A) [Ni(H2O)2(en)2]2+
(B) [Ni(H2O)4(en)]2+ and
(C) [Ni(en)3]2+  is 

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a

(C) > (B) > (A)

b

(C) >(A) > (B)

c

(B) > (A) > (C)

d

(A) > (B) > (C)

answer is B.

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Detailed Solution

Eabsorbed = C > A > B
Ni( en )32+>NiH2O2(en)22+>NiH2O4(en)2+
Number of bidentate ligands are decreases, then its crystal field stabilisation energy decreases. Hence Eabsorbed also decreases.

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