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Q.

The order of melting point of ortho, para, meta-nitrophenol is

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a

p > m > o

b

m > p > o

c

o > m > p

d

p > o > m

answer is B.

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Detailed Solution

Due to intermolecular hydrogen bonding in ortho-isomer, it has least melting point. Due to effective intermolecular hydrogen bonding in para isomer, it has highest melting point among the isomers. So, the order is Para isomer > meta > ortho
  (114℃)          (97℃)            (54 ℃ )
 

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