Q.

The order of pπ-dπ  interaction in the compounds containing bond between Si/P/S/Cl and oxygen is in the order:

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a

S < Cl < P < Si

b

Si < P < S < Cl

c

Si> P > S > Cl

d

P > Si > Cl > S

answer is B.

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Detailed Solution

From Si to Cl in 3rd period, decreasing size increases strength of pπ-dπ bond with oxygen. So the order is,

Si < P < S < Cl

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