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Q.

The order of reactivity of dehydration of alcohol is

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a

1° < 2° > 3°

b

1° > 2° > 3°

c

1° > 2° < 3°

d

1° < 2° < 3°

answer is D.

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Detailed Solution

The order of reactivity is 1° < 2° < 3°.

The creation of carbocations during dehydration is the slowest process, therefore the more stable the carbocation, the more quickly the reaction will occur. Carbocation stability, from highest to lowest:  3° > 2° > 1°.correct option is D.

Step 1: Formation of protonated alcohol 

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Step 2: Formation of carbocation. It is slowest step and rate determining step.

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Step 3: Formation of ethene by elimination of proton 

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The order of reactivity of dehydration of alcohol is