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Q.

The order of reactivity of following alcohols with halogen acids is _____.

A  CH3CH2CH2OH         

B  CH3CH2-CH-OH               |                    CH3

                     CH3                 | C  CH3CH2-C-OH                 |                       CH3

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a

(A)>(B)>(C)

b

(C)>(B)>(A)

c

(B)>(A)>(C)

d

(A)>(C)>(B)

answer is B.

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Detailed Solution

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The reactivity order of alcohols towards halogen acids is 3° > 2° > 1°, since the stability of carbocations is of the order 3° > 2° > 1 °.

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