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The order of reactivity of following alcohols with halogen acids is _____.
$(A) {CH}_{3} {CH}_{2} - {CH}_{2} - OH$
$(B) {CH}_{3} {CH}_{2} - CH - OH | {CH}_{3}$
${CH}_{3} | (C) {CH}_{3} {CH}_{2} - C - OH | {CH}_{3}$

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$(A) > (B) > (C)$

$(C) > (B) > (A)$

$(B) > (A) > (C)$

$(A) > (C) > (B)$

answer is B.

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Detailed Solution

The reactivity order of alcohols towards halogen acids is 3° > 2° > 1°, since the stability of carbocations is of the order 3° > 2° > 1 °.

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