Q.

 The order of  stability of the following free radicals is

(A)

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(B)

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(C)

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(D)

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a

A >B > C > D                

       

b

B > D > C > A       

       

 

c

B > A > D > C  

d

D > C > B > A

        

answer is D.

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Detailed Solution

B - Benzyl free radical…most stable due to resonance.

A - Secondary free radical….6 α-hydrogens…Hyper conjugation

D - Primary free radical….. 3 α- H atoms….Hyper conjugation

C - Primary free radical…..1 α - H atom….Hyper conjugation

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