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The osmatic pressure of a solution containing non-volatile, non-electrolyte solution is 7.6 atm at $27 ° C$ (Assume that molality and molarity are same)

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Molarity of the solution is 0.308M

boiling point of the solution is100.32°C

Freezing point of the solution is −0.573°C

At27°C , the solution is isotonic with 10%(W/V) aqueous urea solution

answer is A, C.

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Detailed Solution

$π = CRT$

$\frac{7.6}{0.081 \times 300} = C \Rightarrow C = 0.308$

$T_{f} M = m, m = 0.308$

$∆ T_{b} = K_{b} \times m$

$T_{b} - T_{b}^{o} = 0.52 \times 0.308$

$T_{b} = (0.52 \times 0.308)$

= 373.16 K

$T_{b} = 100 ° C . 16 ° C$

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