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Q.

The osmotic pressure of a dilute solution of an ionic compound XY in water is four times of a solution of 0.01 M BaCl₂ in water. Assuming complete dissociation of the given ionic compounds in water, the concentration of XY (in mol L^-l) in solution is:

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a

$6 \times 10^{- 2}$

b

$4 \times 10^{- 4}$

c

$16 \times 10^{- 4}$

d

$4 \times 10^{- 2}$

answer is B.

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Detailed Solution

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$We know, π = iCRT; π_{xy} = 4 π_{{BaCl}_{2}}$
$∴ 2 [XY] = 4 \times (0 .01) \times 3$
[XY] = 0.06
$- 6 \times 10^{- 2} mol/L$

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The osmotic pressure of a dilute solution of an ionic compound XY in water is four times of a solution of 0.01 M BaCl2 in water. Assuming complete dissociation of the given ionic compounds in water, the concentration of XY (in mol L-l) in solution is: